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Synthesis of Unsaturated Silyl Heterocycles via an Intramolecular Silyl-Heck Reaction
We report the synthesis of unsaturated silacycles via an intramolecular silyl-Heck reaction. Using palladium catalysis, silicon electrophiles tethered to alkenes cyclize to form 5- and 6-membered silicon heterocycles. The effects of alkene substitution and tether length on the efficiency and regiose...
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| Publicado en: | Organometallics |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2019
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7236810/ https://ncbi.nlm.nih.gov/pubmed/32431470 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.9b00498 |
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