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Lewis Acidic Boranes, Lewis Bases, and Equilibrium Constants: A Reliable Scaffold for a Quantitative Lewis Acidity/Basicity Scale

A quantitative Lewis acidity/basicity scale toward boron‐centered Lewis acids has been developed based on a set of 90 experimental equilibrium constants for the reactions of triarylboranes with various O‐, N‐, S‐, and P‐centered Lewis bases in dichloromethane at 20 °C. Analysis with the linear free...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Mayer, Robert J., Hampel, Nathalie, Ofial, Armin R.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7985883/
https://ncbi.nlm.nih.gov/pubmed/33215760
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003916
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