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Non-canonical radical SAM enzyme chemistry learned from diphthamide biosynthesis

Radical S-adenosylmethionine (SAM) enzymes are a superfamily of enzymes that use SAM and reduced [4Fe-4S] cluster to generate a 5′-deoxyadenosyl radical to catalyze numerous challenging reactions. We have reported a type of non-canonical radical SAM enzymes in the diphthamide biosynthesis pathway. T...

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Detalhes bibliográficos
Publicado no:Biochemistry
Main Authors: Dong, Min, Zhang, Yugang, Lin, Hening
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6893904/
https://ncbi.nlm.nih.gov/pubmed/29708734
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.8b00287
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