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Carbon Dioxide Insertion into Bridging Iron Hydrides: Kinetic and Mechanistic Studies
The reduction of CO(2) to formic acid by transition metal hydrides is a potential pathway to access reactive C1 compounds. To date, no kinetic study has been reported for insertion of a bridging hydride in a weak-field ligated complex into CO(2); such centers have relevance to metalloenzymes that ca...
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| Publicado no: | Eur J Inorg Chem |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6884086/ https://ncbi.nlm.nih.gov/pubmed/31787843 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201801404 |
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