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Access to Metal Centers and Fluxional Hydride Coordination Integral for CO(2) Insertion into [Fe(3)(μ-H)(3)](3+) Clusters
CO(2) insertion into tri(μ-hydrido)triiron(II) clusters ligated by a tris(β-diketiminate) cyclophane is demonstrated to be balanced by sterics for CO(2) approach and hydride accessibility. Time-resolved NMR and UV-vis spectra for this reaction for a complex in which methoxy groups border the pocket...
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| 出版年: | Inorg Chem |
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| 主要な著者: | , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2021
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| 主題: | |
| オンライン・アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8247455/ https://ncbi.nlm.nih.gov/pubmed/33900076 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.1c00244 |
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