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Reactivity of hydride bridges in a high-spin [Fe(3)(μ-H)(3)](3+) cluster: reversible H(2)/CO exchange and Fe–H/B–F bond metathesis
The triiron trihydride complex Fe(3)H(3) L (1) [where L (3–) is a tris(β-diketiminate)cyclophanate] reacts with CO and with BF(3)·OEt(2) to afford (Fe(I)CO)(2)Fe(II)(μ(3)-H)L (2) and Fe(3)F(3) L (3), respectively. Variable-temperature and applied-field Mössbauer spectroscopy support the assignment o...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5443887/ https://ncbi.nlm.nih.gov/pubmed/28603601 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc05583d |
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