High-Frequency Fe-H Vibrations in a Bridging Hydride Complex Characterized by NRVS and DFT

High-spin iron species with bridging hydrides have been detected in species trapped during nitrogenase catalysis, but there are few general methods of evaluating Fe-H bonds in high-spin multinuclear iron systems. Here, we report an (57)Fe nuclear resonance vibrational spectroscopy (NRVS) study on an...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Pelmenschikov, Vladimir, Gee, Leland B., Wang, Hongxin, MacLeod, K. Cory, McWilliams, Sean F., Skubi, Kazimer L., Cramer, Stephen P., Holland, Patrick L.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2018
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6098820/
https://ncbi.nlm.nih.gov/pubmed/29847703
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201804601
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