Vibrational characterization of a diiron bridging hydride complex – a model for hydrogen catalysis

A diiron complex containing a bridging hydride and a protonated terminal thiolate of the form [(μ,κ(2)-bdtH)(μ-PPh(2))(μ-H)Fe(2)(CO)(5)](+) has been investigated through (57)Fe nuclear resonance vibrational spectroscopy (NRVS) and interpreted using density functional theory (DFT) calculations. We re...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Gee, Leland B., Pelmenschikov, Vladimir, Wang, Hongxin, Mishra, Nakul, Liu, Yu-Chiao, Yoda, Yoshitaka, Tamasaku, Kenji, Chiang, Ming-Hsi, Cramer, Stephen P.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159291/
https://ncbi.nlm.nih.gov/pubmed/34094075
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01290d
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