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Kinetics and mechanistic analysis of an extremely rapid carbon dioxide fixation reaction
Carbon dioxide may react with free or metal-bound hydroxide to afford products containing bicarbonate or carbonate, often captured as ligands bridging two or three metal sites. We report the kinetics and probable mechanism of an extremely rapid fixation reaction mediated by a planar nickel complex [...
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| Main Authors: | , , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
National Academy of Sciences
2011
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3029765/ https://ncbi.nlm.nih.gov/pubmed/21220298 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1017430108 |
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