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Reactions of the Terminal Ni(II)–OH Group in Substitution and Electrophilic Reactions with Carbon Dioxide and Other Substrates: Structural Definition of Binding Modes in an Intramolecular Ni(II)…Fe(II) Bridged Site
A singular feature of the catalytic C-cluster of carbon monoxide dehydrogenase is a sulfide-bridged Ni⋯Fe locus where substrate is bound and transformed in the reversible reaction CO + H(2)O ⇌ CO(2) + 2H(+) + 2e(−). A similar structure has been sought in this work. Mononuclear planar Ni(II) complexe...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3031429/ https://ncbi.nlm.nih.gov/pubmed/20218565 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1003125 |
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