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Lewis Acid Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Carbon Centers
The design and gram‐scale synthesis of a cyclohexa‐1,4‐diene‐based surrogate of isobutene gas is reported. Using the highly electron‐deficient Lewis acid B(C(6)F(5))(3), application of this surrogate in the hydromethallylation of electron‐rich styrene derivatives provided sterically congested quater...
Shranjeno v:
| izdano v: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
John Wiley and Sons Inc.
2019
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6856816/ https://ncbi.nlm.nih.gov/pubmed/31449730 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201909852 |
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