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Facile C=O Bond Splitting of Carbon Dioxide Induced by Metal–Ligand Cooperativity in a Phosphinine Iron(0) Complex
New iron complexes [Cp*FeL](−) (1‐σ and 1‐π, Cp*=C(5)Me(5)) containing the chelating phosphinine ligand 2‐(2′‐pyridyl)‐4,6‐diphenylphosphinine (L) have been prepared, and found to undergo facile reaction with CO(2) under ambient conditions. The outcome of this reaction depends on the coordination mo...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6856682/ https://ncbi.nlm.nih.gov/pubmed/31441566 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201909240 |
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