A Phosphinine‐Derived 1‐Phospha‐7‐Bora‐Norbornadiene: Frustrated Lewis Pair Type Activation of Triple Bonds

Salt metathesis of 1‐methyl‐2,4,6‐triphenylphosphacyclohexadienyl lithium and chlorobis(pentafluorophenyl)borane affords a 1‐phospha‐7‐bora‐norbornadiene derivative 2. The C≡N triple bonds of nitriles insert into the P−B bond of 2 with concomitant C−B bond cleavage, whereas the C≡C bonds of phenylac...

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Publicat a:Chemistry
Autors principals: Leitl, Julia, Jupp, Andrew R., Habraken, Evi R. M., Streitferdt, Verena, Coburger, Peter, Scott, Daniel J., Gschwind, Ruth M., Müller, Christian, Slootweg, J. Chris, Wolf, Robert
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
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Full Papers
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7383905/
https://ncbi.nlm.nih.gov/pubmed/32052879
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000266
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