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New Insights in Frustrated Lewis Pair Chemistry with Azides

The geminal frustrated Lewis pair (FLP) tBu(2)PCH(2)BPh(2) (1) reacts with phenyl‐, mesityl‐, and tert‐butyl azide affording, respectively, six, five, and four‐membered rings as isolable products. DFT calculations revealed that the formation of all products proceeds via the six‐membered ring structu...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Boom, Devin H. A., Jupp, Andrew R., Nieger, Martin, Ehlers, Andreas W., Slootweg, J. Chris
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6851766/
https://ncbi.nlm.nih.gov/pubmed/31497899
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201902710
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