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Facile C=O Bond Splitting of Carbon Dioxide Induced by Metal–Ligand Cooperativity in a Phosphinine Iron(0) Complex
New iron complexes [Cp*FeL](−) (1‐σ and 1‐π, Cp*=C(5)Me(5)) containing the chelating phosphinine ligand 2‐(2′‐pyridyl)‐4,6‐diphenylphosphinine (L) have been prepared, and found to undergo facile reaction with CO(2) under ambient conditions. The outcome of this reaction depends on the coordination mo...
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| Publicat a: | Angew Chem Int Ed Engl |
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| Autors principals: | , , , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
John Wiley and Sons Inc.
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6856682/ https://ncbi.nlm.nih.gov/pubmed/31441566 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201909240 |
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