Enantioselective Radical Construction of 5-Membered Cyclic Sulfonamides by Metalloradical C–H Amination

Both arylsulfonyl and alkylsulfonyl azides can be effectively activated by the cobalt(II) complexes of D(2)-symmetric chiral amidoporphyrins for enantioselective radical 1,5-C–H amination to stereoselectively construct 5-membered cyclic sulfonamides. In addition to C–H bonds with varied electronic p...

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Publicado no:J Am Chem Soc
Main Authors: Hu, Yang, Lang, Kai, Li, Chaoqun, Gill, Joseph B., Kim, Isaac, Lu, Hongjian, Fields, Kimberly B., Marshall, McKenzie, Cheng, Qigan, Cui, Xin, Wojtas, Lukasz, Zhang, X. Peter
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6854306/
https://ncbi.nlm.nih.gov/pubmed/31622088
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b08894
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