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New-Generation D(2)-Symmetric Chiral Porphyrins for Cobalt(II)-Based Metalloradical Catalysis: Catalyst Engineering by Distal Bridging

Novel D(2)-symmetric chiral amidoporphyrins with alkyl bridges across two chiral amide units on both sides of the porphyrin plane (designated as “HuPhyrin”) have been effectively constructed in a modular fashion to permit variation of bridge length. The Co(II) complexes of HuPhyrin, [Co(HuPhyrin)],...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Hu, Yang, Lang, Kai, Tao, Jingran, Marshall, McKenzie K., Cheng, Qigan, Cui, Xin, Wojtas, Lukasz, Zhang, X. Peter
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6456056/
https://ncbi.nlm.nih.gov/pubmed/30601601
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201812379
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