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Flavinium Catalysed Photooxidation: Detection and Characterization of Elusive Peroxyflavinium Intermediates

Flavin‐based catalysts are photoactive in the visible range which makes them useful in biology and chemistry. Herein, we present electrospray‐ionization mass‐spectrometry detection of short‐lived intermediates in photooxidation of toluene catalysed by flavinium ions (Fl(+)). Previous studies have sh...

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Publicado en:Angew Chem Int Ed Engl
Main Authors: Zelenka, Jan, Cibulka, Radek, Roithová, Jana
Formato: Artigo
Idioma:Inglês
Publicado: John Wiley and Sons Inc. 2019
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6852162/
https://ncbi.nlm.nih.gov/pubmed/31364790
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201906293
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