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Flavinium Catalysed Photooxidation: Detection and Characterization of Elusive Peroxyflavinium Intermediates

Flavin‐based catalysts are photoactive in the visible range which makes them useful in biology and chemistry. Herein, we present electrospray‐ionization mass‐spectrometry detection of short‐lived intermediates in photooxidation of toluene catalysed by flavinium ions (Fl(+)). Previous studies have sh...

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Détails bibliographiques
Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: Zelenka, Jan, Cibulka, Radek, Roithová, Jana
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2019
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6852162/
https://ncbi.nlm.nih.gov/pubmed/31364790
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201906293
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