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Flavinium Catalysed Photooxidation: Detection and Characterization of Elusive Peroxyflavinium Intermediates

Flavin‐based catalysts are photoactive in the visible range which makes them useful in biology and chemistry. Herein, we present electrospray‐ionization mass‐spectrometry detection of short‐lived intermediates in photooxidation of toluene catalysed by flavinium ions (Fl(+)). Previous studies have sh...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Zelenka, Jan, Cibulka, Radek, Roithová, Jana
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6852162/
https://ncbi.nlm.nih.gov/pubmed/31364790
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201906293
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