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Oxidant speciation and anionic ligand effects in the gold-catalyzed oxidative coupling of arenes and alkynes
The mechanism of the gold-catalyzed oxidative cross-coupling of arenes and alkynes has been studied in detail combining stoichiometric experiments with putative reaction intermediates and DFT calculations. Our data suggest that ligand exchange between the alkyne, the Au(i)-catalyst and the hypervale...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6844217/ https://ncbi.nlm.nih.gov/pubmed/31803420 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02372k |
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