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Iridium-Catalyzed, β-Selective C(sp(3))-H Silylation of Aliphatic Amines To Form Silapyrrolidines and 1,2-Amino Alcohols
The functionalization of unactivated C(sp(3))-H bonds of aliphatic amines catalyzed by transition-metal complexes is important because amine-based functionality is present in a majority of biologically active molecules and commercial pharmaceuticals. However, such reactions are underdeveloped and ch...
Enregistré dans:
| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2018
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6839912/ https://ncbi.nlm.nih.gov/pubmed/30354144 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b10428 |
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