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Intramolecular azavinyl carbene-triggered rearrangement of furans

An intramolecular rhodium-catalyzed reaction of 1-tosyl-1,2,3-triazoles with furans has been explored. The tosylimino functionality was found to play a significant chemical role participating in the subsequent domino-transformations of a key reaction intermediate. One of the reaction pathways leads...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Makarov, Anton S., Uchuskin, Maxim G., Hashmi, A. Stephen K.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6839507/
https://ncbi.nlm.nih.gov/pubmed/31803433
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02299f
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