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Why Do Five Ga(+) Cations Form a Ligand‐Stabilized [Ga(5)](5+) Pentagon and How Does a 5:1 Salt Pack in the Solid State?
The reaction of the Ga(+) source [Ga(PhF)(2)](+)[Al(OR(F))(4)](−) with the neutral σ‐donor ligand dmap (4‐Me(2)N‐C(6)H(4)N) produces the unexpectedly large and fivefold positively charged cluster cation salt [Ga(5)(dmap)(10)](5+)([Al(OR(F))(4)](−))(5). It includes a regular and planar Ga(5) pentagon...
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| Publicat a: | Angew Chem Int Ed Engl |
|---|---|
| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
John Wiley and Sons Inc.
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6790617/ https://ncbi.nlm.nih.gov/pubmed/31369694 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201907974 |
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