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First experimental evidence for the elusive tetrahedral cations [EP(3)](+) (E = S, Se, Te) in the condensed phase
Condensed phase access to the unprecedented tetrahedral cations [EP(3)](+) (E = S, Se, Te) was achieved through the reaction of ECl(3)[WCA] with white phosphorus ([WCA](–) = [Al(OR(F))(4)](–) and [F(Al(OR(F))(3))(2)](–); –R(F) = –C(CF(3))(3)). Previously, [EP(3)](+) was only known from gas phase MS...
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| Udgivet i: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7006506/ https://ncbi.nlm.nih.gov/pubmed/32055385 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03915e |
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