First experimental evidence for the elusive tetrahedral cations [EP(3)](+) (E = S, Se, Te) in the condensed phase

Condensed phase access to the unprecedented tetrahedral cations [EP(3)](+) (E = S, Se, Te) was achieved through the reaction of ECl(3)[WCA] with white phosphorus ([WCA](–) = [Al(OR(F))(4)](–) and [F(Al(OR(F))(3))(2)](–); –R(F) = –C(CF(3))(3)). Previously, [EP(3)](+) was only known from gas phase MS...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Weis, Philippe, Röhner, David Christopher, Prediger, Richard, Butschke, Burkhard, Scherer, Harald, Weber, Stefan, Krossing, Ingo
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7006506/
https://ncbi.nlm.nih.gov/pubmed/32055385
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03915e
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