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Investigations on non-classical silylium ions leading to a cyclobutenyl cation
Instead of yielding the desired non-classical silylium ions, the reactions of different alkenes/alkynes with several [Me(3)Si](+) sources mostly led to oligomerization, or – in the presence of Me(3)SiH – hydrosilylation of the alkenes/alkynes. Yet, from the reaction of 2-butyne with ion-like Me(3)Si...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6419934/ https://ncbi.nlm.nih.gov/pubmed/30997003 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04591g |
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