Why Do Five Ga(+) Cations Form a Ligand‐Stabilized [Ga(5)](5+) Pentagon and How Does a 5:1 Salt Pack in the Solid State?

The reaction of the Ga(+) source [Ga(PhF)(2)](+)[Al(OR(F))(4)](−) with the neutral σ‐donor ligand dmap (4‐Me(2)N‐C(6)H(4)N) produces the unexpectedly large and fivefold positively charged cluster cation salt [Ga(5)(dmap)(10)](5+)([Al(OR(F))(4)](−))(5). It includes a regular and planar Ga(5) pentagon...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Glootz, Kim, Himmel, Daniel, Kratzert, Daniel, Butschke, Burkhard, Scherer, Harald, Krossing, Ingo
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6790617/
https://ncbi.nlm.nih.gov/pubmed/31369694
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201907974
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