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Chemoselective Carbonyl Allylations with Alkoxyallylsiletanes
Alkoxyallylsiletanes are capable of highly chemo- and diastereoselective carbonyl allylsilylations. Reactive substrates include salicylaldehydes and glyoxylic acids. Chemoselectivity in these reactions is thought to arise from a mechanism involving first exchange of the alkyoxy group on silicon with...
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| Publicado no: | J Org Chem |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6767911/ https://ncbi.nlm.nih.gov/pubmed/30811929 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.8b03028 |
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