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Allyl-Nickel Catalysis Enables Carbonyl Dehydrogenation and Oxidative Cycloalkenylation of Ketones
We herein disclose the first report of a first- row transition metal-catalyzed α,β-dehydrogenation of carbonyl compounds using allyl-nickel catalysis. This development overcomes several limitations of previously reported allyl-palladium-catalyzed oxidation, and is further leveraged for the developme...
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Publicado no: | J Am Chem Soc |
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Main Authors: | , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
2019
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7495923/ https://ncbi.nlm.nih.gov/pubmed/30861346 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b02552 |
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