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Allyl-Nickel Catalysis Enables Carbonyl Dehydrogenation and Oxidative Cycloalkenylation of Ketones

We herein disclose the first report of a first- row transition metal-catalyzed α,β-dehydrogenation of carbonyl compounds using allyl-nickel catalysis. This development overcomes several limitations of previously reported allyl-palladium-catalyzed oxidation, and is further leveraged for the developme...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Huang, David, Szewczyk, Suzanne M., Zhang, Pengpeng, Newhouse, Timothy R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7495923/
https://ncbi.nlm.nih.gov/pubmed/30861346
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b02552
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