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Allyl-Palladium Catalyzed Ketone Dehydrogenation Enables Telescoping with Enone α,β-Vicinal Difunctionalization

The telescoping of allyl-palladium catalyzed ketone dehydrogenation with organocuprate conjugate addition chemistry allows for the introduction of aryl, heteroaryl, vinyl, acyl, methyl, and other functionalized alkyl groups chemoselectively to a wide variety of unactivated ketone compounds via their...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Chen, Yifeng, Huang, David, Zhao, Yizhou, Newhouse, Timothy R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5884112/
https://ncbi.nlm.nih.gov/pubmed/28561999
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201704874
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