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A Synthetic Model of Enzymatic [Fe(4)S(4)]–Alkyl Intermediates

[Image: see text] Although alkyl complexes of [Fe(4)S(4)] clusters have been invoked as intermediates in a number of enzymatic reactions, obtaining a detailed understanding of their reactivity patterns and electronic structures has been difficult owing to their transient nature. To address this chal...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Ye, Mengshan, Thompson, Niklas B., Brown, Alexandra C., Suess, Daniel L. M.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2019
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6748666/
https://ncbi.nlm.nih.gov/pubmed/31373801
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b06975
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