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A [4Fe-4S]-Fe(CO)(CN)-L-cysteine intermediate is the first organometallic precursor in [FeFe] hydrogenase H-cluster bioassembly
Biosynthesis of the [FeFe] hydrogenase active site (the “H-cluster”) requires the interplay of multiple proteins and small molecules. Among them, the radical S-adenosyl-methionine enzyme HydG, a tyrosine lyase, has been proposed to generate an Fe(CO)(2)(CN) moiety-containing complex that is eventual...
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| Publié dans: | Nat Chem |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2018
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6380689/ https://ncbi.nlm.nih.gov/pubmed/29632334 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41557-018-0026-7 |
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