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Sacrificial Cobalt−Carbon Bond Homolysis in Coenzyme B(12) as a Cofactor Conservation Strategy
A sophisticated intracellular trafficking pathway in humans is used to tailor vitamin B(12) into its active cofactor forms, and to deliver it to two known B(12-)dependent enzymes. Herein, we report an unexpected strategy for cellular retention of B(12), an essential and reactive cofactor. If methylm...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , , , , , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2018
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6743335/ https://ncbi.nlm.nih.gov/pubmed/30282455 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b08659 |
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