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Total Synthesis and Structural Validation of Phosdiecin A via Asymmetric Alcohol-Mediated Carbonyl Reductive Coupling
The first total synthesis and structural validation of phosdiecin A was accomplished in 13 steps (LLS) through asymmetric iridium-catalyzed alcohol-mediated carbonyl reductive coupling. The present route is the shortest among >30 total and formal syntheses of fostriecin family members.
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6737538/ https://ncbi.nlm.nih.gov/pubmed/31433167 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b07512 |
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