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Palladium-Catalyzed Enantioselective Alkenylation of Enelactams Using a Relay Heck Strategy
In this report, we describe a palladium-catalyzed redox relay Heck process to access optically active alkenylated α,β-unsaturated lactams. Under mild reaction conditions, electron-deficient alkenyl triflates and electron-rich alkenyl iodonium salts undergo enantioselective and site-selective couplin...
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| Udgivet i: | Chemistry |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6731067/ https://ncbi.nlm.nih.gov/pubmed/31216370 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201902813 |
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