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Enantioselective Synthesis of Alkyl Allyl Ethers via Palladium-Catalyzed Redox-Relay Heck Alkenylation of O-Alkyl Enol Ethers

Herein we report a transformation that generates an array of enantiomerically enriched, alkyl allyl ethers. Cyclic, acyclic, and heteroatom-bearing alkenyl triflates undergo an enantioselective, palladium-catalyzed C–C bond formation with diverse acyclic O-alkyl enol ethers in good yields and excell...

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Detalhes bibliográficos
Publicado no:Isr J Chem
Main Authors: Prater, Matthew B., Sigman, Matthew S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7806183/
https://ncbi.nlm.nih.gov/pubmed/33446940
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ijch.201900077
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