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Characterization of a trans–trans Carbonic Acid–Fluoride Complex by Infrared Action Spectroscopy in Helium Nanodroplets
[Image: see text] The high Lewis basicity and small ionic radius of fluoride promote the formation of strong ionic hydrogen bonds in the complexation of fluoride with protic molecules. Herein, we report that carbonic acid, a thermodynamically disfavored species that is challenging to investigate exp...
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Publicado no: | J Am Chem Soc |
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Main Authors: | , , , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
American Chemical
Society
2019
|
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6727381/ https://ncbi.nlm.nih.gov/pubmed/30883095 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b13542 |
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