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Characterization of a trans–trans Carbonic Acid–Fluoride Complex by Infrared Action Spectroscopy in Helium Nanodroplets

[Image: see text] The high Lewis basicity and small ionic radius of fluoride promote the formation of strong ionic hydrogen bonds in the complexation of fluoride with protic molecules. Herein, we report that carbonic acid, a thermodynamically disfavored species that is challenging to investigate exp...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Thomas, Daniel A., Mucha, Eike, Lettow, Maike, Meijer, Gerard, Rossi, Mariana, von Helden, Gert
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2019
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6727381/
https://ncbi.nlm.nih.gov/pubmed/30883095
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b13542
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