Synthesis, Structure, and Hydrogenolysis of Pyridine Dicarbene Iron Dialkyl Complexes

Two methods for the synthesis of bis(imidazol-2-ylidene)pyridine iron dialkyl complexes, (CNC)Fe(CH(2)SiMe(3))(2), have been developed. The first route consists of addition of two equivalents of LiCH(2)SiMe(3) to the iron dihalide complex, (CNC)FeBr(2), while the second relies on addition of the fre...

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Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Organometallics
Egile Nagusiak: Rummelt, Stephan M., Darmon, Jonathan M., Yu, Renyuan Pony, Viereck, Peter, Pabst, Tyler P., Turner, Zoë R., Margulieux, Grant W., Gu, Shunlin, Chirik, Paul J.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2019
Gaiak:
Article
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC6720121/
https://ncbi.nlm.nih.gov/pubmed/31481822
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.9b00382
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