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Synthesis, Structure, and Hydrogenolysis of Pyridine Dicarbene Iron Dialkyl Complexes
Two methods for the synthesis of bis(imidazol-2-ylidene)pyridine iron dialkyl complexes, (CNC)Fe(CH(2)SiMe(3))(2), have been developed. The first route consists of addition of two equivalents of LiCH(2)SiMe(3) to the iron dihalide complex, (CNC)FeBr(2), while the second relies on addition of the fre...
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| Veröffentlicht in: | Organometallics |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6720121/ https://ncbi.nlm.nih.gov/pubmed/31481822 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.9b00382 |
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