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Catalytic Hydrogenation Activity and Electronic Structure Determination of Bis(arylimidazol-2-ylidene)pyridine Cobalt Alkyl and Hydride Complexes
The bis(arylimidazol-2-ylidene)pyridine cobalt methyl complex, ((iPr)CNC)CoCH(3), was evaluated for the catalytic hydrogenation of alkenes. At 22 °C and 4 atm of H(2) pressure, ((iPr)CNC)CoCH(3) is an effective pre-catalyst for the hydrogenation of sterically hindered, unactivated alkenes such as tr...
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| Hoofdauteurs: | , , , , , , |
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| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2013
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3799879/ https://ncbi.nlm.nih.gov/pubmed/23968297 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja406608u |
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