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Catalytic Hydrogenation Activity and Electronic Structure Determination of Bis(arylimidazol-2-ylidene)pyridine Cobalt Alkyl and Hydride Complexes

The bis(arylimidazol-2-ylidene)pyridine cobalt methyl complex, ((iPr)CNC)CoCH(3), was evaluated for the catalytic hydrogenation of alkenes. At 22 °C and 4 atm of H(2) pressure, ((iPr)CNC)CoCH(3) is an effective pre-catalyst for the hydrogenation of sterically hindered, unactivated alkenes such as tr...

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Detalhes bibliográficos
Main Authors: Yu, Renyuan Pony, Darmon, Jonathan M., Milsmann, Carsten, Margulieux, Grant W., E. Stieber, S. Chantal, DeBeer, Serena, Chirik, Paul J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3799879/
https://ncbi.nlm.nih.gov/pubmed/23968297
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja406608u
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