Bis(imino)pyridine Iron Dinitrogen Compounds Revisited: Differences in Electronic Structure Between Four- and Five-Coordinate Derivatives

The electronic structures of the four- and five-coordinate aryl-substituted bis(imino)pyridine iron dinitrogen complexes, ((iPr)PDI)FeN(2) and ((iPr)PDI)Fe(N(2))(2) ((iPr)PDI = 2,6-(2,6-(i)Pr(2)-C(6)H(3)-N=CMe)(2)C(5)H(3)N), have been investigated by a combination of spectroscopic techniques (NMR, M...

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Detalhes bibliográficos
Main Authors: E. Stieber, S. Chantal, Milsmann, Carsten, Hoyt, Jordan M., Turner, Zoë R., Finkelstein, Kenneth D., Wieghardt, Karl, DeBeer, Serena, Chirik, Paul J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3366276/
https://ncbi.nlm.nih.gov/pubmed/22675236
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om201212m
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