Synthesis, Structure, and Hydrogenolysis of Pyridine Dicarbene Iron Dialkyl Complexes

Two methods for the synthesis of bis(imidazol-2-ylidene)pyridine iron dialkyl complexes, (CNC)Fe(CH(2)SiMe(3))(2), have been developed. The first route consists of addition of two equivalents of LiCH(2)SiMe(3) to the iron dihalide complex, (CNC)FeBr(2), while the second relies on addition of the fre...

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Publicado en:Organometallics
Main Authors: Rummelt, Stephan M., Darmon, Jonathan M., Yu, Renyuan Pony, Viereck, Peter, Pabst, Tyler P., Turner, Zoë R., Margulieux, Grant W., Gu, Shunlin, Chirik, Paul J.
Formato: Artigo
Idioma:Inglês
Publicado: 2019
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6720121/
https://ncbi.nlm.nih.gov/pubmed/31481822
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.9b00382
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