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Combinatorial biosynthesis and the basis for substrate promiscuity in class I diterpene synthases
Terpene synthases are capable of mediating complex reactions, but fundamentally simply catalyze lysis of allylic diphosphate esters with subsequent deprotonation. Even with the initially generated tertiary carbocation this offers a variety of product outcomes, and deprotonation further can be preced...
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| Veröffentlicht in: | Metab Eng |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6717049/ https://ncbi.nlm.nih.gov/pubmed/31220664 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ymben.2019.06.008 |
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