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Rhodium-Catalyzed Asymmetric Hydroamination of Allyl Amines
A Rh-catalyzed enantioselective hydroamination of allylamines using a chiral BIPHEP-type ligand is reported. Enantioenriched 1,2-diamines are formed in good yields and with excellent enantioselectivities. A diverse array of nucleophiles and amine directing groups are demonstrated, including deprotec...
Enregistré dans:
| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2019
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6693864/ https://ncbi.nlm.nih.gov/pubmed/30614700 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b09811 |
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