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Asymmetric Induction and Enantiodivergence in Catalytic Radical C−H Amination via Enantiodifferentiative H-Atom Abstraction and Stereoretentive Radical Substitution
Control of enantioselectivity remains a major challenge in radical chemistry. The emergence of metalloradical catalysis (MRC) offers a conceptually new strategy for addressing this and other outstanding issues. Through the employment of D(2)-symmetric chiral amidoporphyrins as the supporting ligands...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6687549/ https://ncbi.nlm.nih.gov/pubmed/31280562 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b05850 |
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