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Ring‐Opening Regio‐, Diastereo‐, and Enantioselective 1,3‐Chlorochalcogenation of Cyclopropyl Carbaldehydes

meso‐Cyclopropyl carbaldehydes are treated in the presence of an organocatalyst with sulfenyl and selenyl chlorides to afford 1,3‐chlorochalcogenated products. The transformation is achieved by a merged iminium–enamine activation. The enantioselective desymmetrization reaction, leading to three adja...

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Bibliografiset tiedot
Julkaisussa:Chemistry
Päätekijät: Wallbaum, Jan, Garve, Lennart K. B., Jones, Peter G., Werz, Daniel B.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: John Wiley and Sons Inc. 2016
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC6680189/
https://ncbi.nlm.nih.gov/pubmed/27868248
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201605265
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