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Probing the Structural and Electronic Effects on the Origin of π-Facial Stereoselectivity in 1-Methylphosphole 1-Oxide Cycloadditions and Cyclodimerization

[Image: see text] We have examined the π-facial stereoselectivity in the Diels–Alder reactions of phosphole oxides computationally. The experimentally observed syn-cycloadditions have been rationalized with the Cieplak model and distortion–interaction model. The natural bond orbital analysis suggest...

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Detalhes bibliográficos
Publicado no:ACS Omega
Main Authors: Bhai, Surjit, Jana, Kalyanashis, Ganguly, Bishwajit
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2018
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6645475/
https://ncbi.nlm.nih.gov/pubmed/31459205
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.8b01165
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