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Probing the Structural and Electronic Effects on the Origin of π-Facial Stereoselectivity in 1-Methylphosphole 1-Oxide Cycloadditions and Cyclodimerization
[Image: see text] We have examined the π-facial stereoselectivity in the Diels–Alder reactions of phosphole oxides computationally. The experimentally observed syn-cycloadditions have been rationalized with the Cieplak model and distortion–interaction model. The natural bond orbital analysis suggest...
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| Veröffentlicht in: | ACS Omega |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
American Chemical Society
2018
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| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6645475/ https://ncbi.nlm.nih.gov/pubmed/31459205 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.8b01165 |
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